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A New Route to Quantum-Scale Structures through a Novel Enhanced Germanium Diffusion Mechanism

George C. Wang, Ping Lu, Keshab Sapkota, Andrew Baczewski, Quinn Campbell, Peter A. Schultz, Kevin Jones, Emily Turner et al.

2021

Abstract

This project sought to develop a fundamental understanding of the mechanisms underlying a newly observed enhanced germanium (Ge) diffusion process in silicon germanium (SiGe) semiconductor nanostructures during thermal oxidation. Using a combinati on of oxidation - diffusion experiments, high resolution imaging, and theoretical modeling, a model for the enhanced Ge diffusion mechanism was proposed . Additionally, a nanofabrication approach utilizing this enhanced Ge diffusion mechanism was shown to be applicable to arbitrary 3D shapes, leading to the fabrication of stacked silicon quantum dots embedded in SiGe nanopillars. A new wet etch - based method for preparing 3D nanostructures for high - resolution imaging free of obscuring material or damage was als o developed. These results enable a new method for the controlled and scalable fabrication of on - chip silicon nanostructures with sub - 10 nm dimensions needed for next generation microelectronics, including low energy electronics, quantum computing, sensors , and integrated photonics.

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