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Microstructural and Chemical Characterization of Industrial Ferronickel Produced by the RKEF Process Using SEM–EDS Analysis

Gashi ZB, Mateeva J

2026

Abstract

Abstract Ferronickel (Fe–Ni) is a key ferroalloy used in stainless steel production, predominantly produced from lateritic ores via the rotary kiln–electric furnace (RKEF) process. In this study, the microstructural features and localized chemical composition of industrial ferronickel produced in Kosovo were investigated using scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDS).The results reveal a heterogeneous metallic matrix with dendritic morphology, typical of rapid solidification under industrial conditions. SEM observations indicate the presence of non-metallic inclusions embedded within the Fe–Ni matrix. EDS analysis confirms that iron is the dominant element, while nickel is relatively homogeneously distributed, suggesting effective alloying during smelting. Localized oxygen- rich regions are associated with oxide inclusions, likely originating from incomplete slag–metal separation and residual oxides from the reduction process. The presence of carbon is attributed to carbothermic reduction in the rotary kiln stage. The results indicate that reduction reactions are advanced but not fully completed, which is consistent with industrial RKEF operation. By combining microstructural observations with industrial slag composition and process parameters, this study provides insight into the relationship between process conditions, inclusion formation, and alloy heterogeneity. The findings contribute to improved understanding of…

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