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Key adsorbents and influencing factors in the adsorption of micro- and nanoplastics: A review

García-Rollán M, Sanz-Santos E, Belver C, Bedia J

Journal of environmental management, 2025

Abstract

Microplastics and nanoplastics (MNPs) are emerging contaminants in drinking water sources that pose serious risks to human health and ecosystems. Several removal strategies, such as adsorption, exist but present challenges for their industrial scalability. This review provides a concise overview of MNP adsorption mechanisms and highlights the limited but critical exploration of column adsorption in the literature, emphasizing its importance for large-scale applications. Special attention is given to carbon-based materials due to their cost-effectiveness, environmental friendliness and sustainability. Other adsorbents (e.g., metal-organic frameworks, clays) are also discussed for their promising performance in realistic water matrixes. To predict and optimize the efficiency of adsorbents, leading simulation models are reviewed. Taken together, this work provides a comprehensive overview of the fundamental factors, such as adsorption mechanisms, adsorbent selection and experimental conditions, to optimize MNP adsorption. By highlighting the underexplored area of column-based processes, it provides valuable information to advance adsorption as a viable industrial-scale solution for MNP contamination.

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