Surface chemistry-engineered perovskite quantum dot photovoltaics
Abstract
The discovery and synthesis of colloidal quantum dots (QDs) was awarded the Nobel Prize in Chemistry in 2023. Recently, the development of bulk metal halide perovskite semiconductors has generated intense interest in their corresponding perovskite QDs. QDs, more broadly known as nanocrystals, constitute a new class of materials that differ from both molecular and bulk materials. They have rapidly advanced to the forefront of optoelectronic applications owing to their unique size-, composition-, surface- and process-dependent optoelectronic properties. More importantly, their ultrahigh surface-area-to-volume ratio enables various surface chemistry engineering strategies to tune and optimize their optoelectronic properties. Finally, three-dimensional confined QDs, offering nearly perfect photoluminescent quantum yield, slow hot-carrier cooling time, especially their colloidal synthesis and processing using industrially friendly solvents, have revolutionized the fields of electronics, photonics, and optoelectronics. Particularly, in emerging perovskite QD-based PVs, the advancement of surface chemistry has boosted the record power conversion efficiency (PCE) to 19.1% within a five-year period, surpassing all other colloidal QD photovoltaics (PVs). Given the rapid enhancement of device performances, perovskite QD PVs have attracted significant attention. Further study of semiconducting perovskite QDs will lead to advanced surface structures, a deeper understanding of halide…
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