Quantum mechanics for natural philosophers (I)
Abstract
The quantum revolution began in 1900 with a novel solution to what might seem to be one of the minor puzzles of theoretical physics, the problem of black-body radiation: the problem of the interaction of those two sorts of entity which figure in the dualist ontology of late classical physics. The trouble for classical physics was that the facts about a black body's capacity to absorb and emit radiation defied thermodynamic explanation. The best that classical physics could do was to get the facts wrong and to generate paradox. So what was the problem of black-body radiation and why was it considered to be so puzzling? First, what is a black body? Some bodies absorb and emit radiation more readily than others. A mirror is a poor absorber of radiation in the form of light, a piece of coal is a good one. A good absorber of radiation in the form of light is ‘blacker’ than one that is not. One can extend the metaphor to radiation outside the visible range. Clearly, a body that is ‘blacker’ than another for one range of radiation frequencies need not be ‘blacker’ for all frequencies. A body's ‘blackness’ will, in general, depend on its chemical structure. But we can imagine a body whose blackness is maximal for all wavelengths. Such a body, if it exists, has a blackness which is independent of its chemical structure. We call it a black body. Two interesting questions are: first, are there bodies in Nature which are uniformly and maximally black for all wavelengths? and second, how…
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