Unravelling superstructure and electronic ordering in LiNiO2 bulk single crystals grown by optical floating zone technique
Abstract
Although there have been several studies on the powder form, there has yet to be a report on the bulk crystal growth and its property studies of LiNiO2. In the present study, we report the first successful growth of a LiNiO2 single crystal by employing the optical floating-zone technique. Structural properties have been studied using single-crystal X-ray diffraction (XRD). The structural refinement of the single-crystal XRD data, along with the Laue diffraction patterns, confirms that this system crystallizes in a rhombohedral unit cell in space group R3m and the presence of a single grain along the length of the grown crystal. Furthermore, for the first time, we have observed and determined their superstructures as a function of temperature using single-crystal XRD. We have also conducted a study using the high flux of synchrotron X-rays to demonstrate the mechanism which drives the superstructure witnessed by the single-crystal XRD. Resonant elastic X-ray scattering was used to confirm the superstructure and the mixed valence state of different Ni sites. No additional ordering phenomena were observed, including magnetic or electronic ordering. Our study demonstrates the optimization of LiNiO2 growth parameters and provides information about atomic and electronic ordering in the system, including the onset of a superstructure phase. This will provide a basis for further work in developing improved cathode materials and understanding quantum spin liquids.
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