Rare-Earth Single-Atom Catalysts: A New Frontier in Photo/Electrocatalysis
Abstract
Single-atom catalysts (SACs) provide well-defined active sites with 100% atom utilization, and can be prepared using a wide range of support materials. Therefore, they are attracting global attention, especially in the fields of energy conversion and storage. To date, research has focused on transition-metal and precious-metal-based SACs. More recently, rare-earth (RE)-based SACs have emerged as a new frontier in photo/electrocatalysis owing to their unique electronic structure arising from the spin-orbit coupling of the 4f and valence orbitals, unsaturated coordination environment, and unique behavior as charge-transport bridges. However, a systematic review on the role of the RE active sites, catalytic mechanisms, and synthetic methods for RE SACs is lacking. Therefore, in this review, the latest developments in RE SACs having applications in photo/electrocatalysis are summarized and discussed. First, the theoretical advantages of RE SACs for photo/electrocatalysis are briefly introduced, focusing on the roles of the 4f orbitals and coupled energy levels. In addition, the most recent research progress on RE SACs is summarized for several important photo/electrocatalytic reactions and the corresponding catalytic mechanisms are discussed. Further, the synthetic strategies for the production of RE SACs are reported. Finally, challenges for the development of RE SACs are highlighted, along with future research directions and perspectives.
How strong is the evidence?
Evidence Hub reads this as a systematic review, done in people. Its evidence level is 1 of 5 (Highest · pooled evidence). Pooled evidence from several studies sits at the top of the evidence pyramid.
Read the paper
Related studies
- Preliminary Toxicity Analysis of 3DCRT versus IMRT on the High Dose Arm of the RTOG 0126 Prostate Cancer Trial
- Adaptive Radiotherapy for Head and Neck Cancer: Initial Clinical Outcomes from a Prospective Trial
- American Association of Physicists in Medicine Task Group 263: Standardizing Nomenclatures in Radiation Oncology
- Motion Management Strategies and Technical Issues Associated with Stereotactic Body Radiotherapy of Thoracic and Upper Abdominal Tumors: A Review from NRG Oncology
- High-dose-rate interstitial brachytherapy as a monotherapy for localized prostate cancer: treatment description and preliminary results of a phase I/II clinical trial
- Highly efficient training, refinement, and validation of a knowledge-based plan quality control system for radiotherapy clinical trials
Go deeper in Evidence Hub
Evidence Hub adds a study data sheet (design, sample size, evidence level, key numbers), an AI summary and a chat grounded in the paper's text.