Pristine and Doped MoS2 Monolayers as Potential HCN Gas Sensors: A DFT Study
Abstract
Two-dimensional transition metal dichalcogenides (TMDCs) have been extensively investigated due to their tunable properties. In this work, density functional theory (DFT) is employed to investigate the adsorption behavior and sensing characteristics of HCN on pristine and doped MoS2 monolayers (X-MoS2, where X = P, N, Si, Al, B, Cl). The structural, electronic, and optical characteristics of all systems are examined to study the sensing properties of various doped MoS2 monolayers. In particular, the Al-MoS2 system demonstrates the strongest adsorption characterized by chemisorption, while the remaining systems show interactions of physisorption type. Recovery time and changes in electronic and optical properties reveal that Si-MoS2 possesses an ultrafast response of the order of microseconds, while Al-MoS2 exhibits a significantly longer recovery time, making it unsuitable for reusable sensors. P-MoS2, Si-MoS2, and Al-MoS2 monolayers show pronounced changes in their properties after HCN adsorption. To explore tunability in adsorption strength and recovery behavior, systems with two and three dopant atoms are further studied for P, Si, and Al doping. The results indicate that double doping enhances adsorption strength, whereas triple symmetric doping weakens it. Based on adsorption energy, recovery time, and electronic response, 2P-MoS2 and 3Al-MoS2 are identified as promising candidates for electrochemical and chemiresistive sensing of HCN. Additionally, the observed optical…
Read the paper
Related studies
- Nano Biosensors: Properties, applications and electrochemical techniques
- Electrochemically Synthesized MIP Sensors: Applications in Healthcare Diagnostics
- Toward a Harmonization for Using in situ Nutrient Sensors in the Marine Environment
- Electrochemical determination of rutin by using NiFe2O4 nanoparticles-loaded reduced graphene oxide
- Application of Polyoxometalate-based composites for sensor systems: A review
- Sensitive Electrochemical and Thermal Detection of Human Noroviruses Using Molecularly Imprinted Polymer Nanoparticles Generated against a Viral Target
Go deeper in Evidence Hub
Evidence Hub adds a study data sheet (design, sample size, evidence level, key numbers), an AI summary and a chat grounded in the paper's text.